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21.
摘有机化学是面向工科专业开设的一门基础课程,因授课教师的知识背景不同,所以在教学过程中应因地适宜考虑教学方案,提高教学质量。文章根据作者在有机化学授课上的教学实践与经验,浅议高分子材料学在有机化学教学中提高学生兴趣与课堂效率的作用。 相似文献
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Xiantao Lei Hong‐Yan Xie Chang Xu Xiaoyu Liu Xiaoan Wen Hongbin Sun Qing‐Long Xu 《Advanced Synthesis \u0026amp; Catalysis》2016,358(12):1892-1896
An intramolecular palladium(II)‐catalyzed dearomative arylation reaction of indoles via C H bond functionalization was developed, providing access to structurally novel spiroindolenines with moderate to good yields. A one‐pot process for the synthesis of spiroindoline derivatives was also realized.
24.
Copper salts, which are abundant, relatively inexpensive and possess low toxicity, have long been used as versatile catalysts for various reactions in organic synthesis. Recently, the development of Cu‐catalyzed or ‐mediated C H functionalization reactions has gained significant attention. Since the pioneering work of Daugulis on the introduction of 8‐aminoquinoline and picolinic acid auxiliaries as removable directing groups in transition metal‐catalyzed C H bond activations, the combination of copper salts with these bidentate directing groups has emerged as an innovative strategy for the construction of carbon‐carbon or carbon‐heteroatom bonds through C H bond cleavage. In addition to the 8‐aminoquinoline and picolinamide systems, several other bidentate directing groups including the 2‐aminophenyloxazoline group by Yu and Dai and the PIP system by Shi, have been developed as well. This review intends to cover most of the recent advances on copper‐catalyzed or ‐mediated direct sp2 and sp3 C H bond functionalizations assisted by these bidentate directing groups. The major achievements in this area are discussed and catalogued by the type of bonds formed (C C, C O, C N, C S, C P etc.). Special attention is paid to the reaction mechanisms. Selected examples of substrates are listed as well. In addition, a personal outlook is given at the end.
25.
Huan Sun Yi Zhang Ping Chen Yun‐Dong Wu Xinhao Zhang Yong Huang 《Advanced Synthesis \u0026amp; Catalysis》2016,358(12):1946-1957
The direct functionalization of inert sp3 C H bonds is limited to a few bond types. Although the activation of sp3 C H bonds can be accomplished under mild conditions using palladium catalysts, the subsequent functionalization is not trivial due to the high energy required to convert palladium(II) to palladium(IV). We have systematically studied the palladium oxidation using computation‐guided experiments for reactions involving strong chelation control. We find that a mild external ligand could significantly accelerate the oxidation of palladium(II) to palladium(IV) for strong bidentate directing groups. The acceleration is believed to be a result of ligand stabilization of both the palladium(II) and palladium(IV) intermediates.
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The palladium‐catalyzed ketone‐directed dual sp2 C H activation and sp3 C H functionalization has been applied for fullerene functionalization for the first time. The sec‐alkyl aryl ketones have been exploited to react with [60]fullerene (C60) to provide the novel and scarce C60‐fused tetralones. The combined use of a highly active cationic palladium(II) catalyst and trifluoromethanesulfonic acid is crucial for the improvement of the reaction yield. A plausible reaction mechanism leading to the observed products has been proposed, and the electrochemistry of the fullerene products has also been investigated.
27.
Feihua Luo Jun Yang Zhengkai Li Haifeng Xiang Xiangge Zhou 《Advanced Synthesis \u0026amp; Catalysis》2016,358(6):887-893
A palladium(II)‐catalyzed direct arylation of methylene C(sp3) H bonds by 2‐methyl‐7‐aminobenzoxazole as an effective auxiliary is reported. This process exhibited high beta‐site selectivity, broad substrate scope, and compatibility with different functional groups with moderate to high yields up to 89%.
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Krishnamoorthy Muralirajan Ramajayam Kuppusamy Sekar Prakash Chien‐Hong Cheng 《Advanced Synthesis \u0026amp; Catalysis》2016,358(5):774-783
A green atom‐economical method for the synthesis of highly functionalized 1‐amino and 1‐carbon substituted isoquinolines from the reaction of N′‐hydroxybenzimidamides and aryl ketoximes, respectively, with alkynes via pentamethylcyclopentadienylcobalt(III)‐catalyzed C H/N O bond activation is described. The external oxidant‐free annulation reaction uses the =NOH moiety in N′‐hydroxybenzimidamides or N‐aromatic ketone oximes as the directing group and internal oxidant. This first row transition metal‐catalyzed annulation serves as an efficient alternative for the synthesis of isoquinolines, as water is the only by‐product and expensive noble metals such as rhodium(III), iridium(III), palladium(II), and ruthenium(II) are not required. The reaction proceeds via C H activation, alkyne insertion, reductive elimination, and N O activation.
29.
Mangfei Yu Qian Zhang Gong Li Jingwen Yuan Ning Zhang Rui Zhang Yongjiu Liang Dewen Dong 《Advanced Synthesis \u0026amp; Catalysis》2016,358(3):410-416
A facile and efficient one‐pot synthesis of isoxazol‐3(2H)‐ones has been developed starting from α‐acyl cinnamides and tosyliminophenyliodinane catalyzed by copper(II) acetate [Cu(OAc)2] under very mild conditions involving a tandem aza‐Michael addition and intramolecular cyclization sequence.
30.
Special‐purpose solutions in the fire‐protective evaluation of construction details Very often components or construction details in existing buildings but also in new buildings cannot be evaluated with regard to its fire resistance ability considering established technical building regulations. There are no regulations for the evaluation of such components or construction details as these specific construction details have not been evaluated by a certified test authority. However, these components and construction details very often can be classified in fire resistance classes e. g. by evaluating fire tests, with regard to DIN 4102‐4, on the basis of similar proof of usability or only by pragmatic considerations. Since introducing the technical approval of the fire protection Eurocodes more often engineering methods of fire protection are used based on these Eurocodes by using temperature assessment in order to secure the evaluation results. Within this essay we show methods and ways of fire‐protective evaluation for components and construction details. The approach of proof including dimensions of possible upgrade measurements if necessary are being illustrated by examples of use out of practical experience. At the same time different materials such as steel, concrete and wood will be treated with different fire‐proof products. The essay is to explain ways of evaluation of components and construction details involving fire‐proof requirements including upgrade measurements also especially for existing buildings. 相似文献